dc.contributor.author |
Shekurov R. |
|
dc.contributor.author |
Miluykov V. |
|
dc.contributor.author |
Kataeva O. |
|
dc.contributor.author |
Krivolapov D. |
|
dc.contributor.author |
Sinyashin O. |
|
dc.contributor.author |
Gerasimova T. |
|
dc.contributor.author |
Katsyuba S. |
|
dc.contributor.author |
Kovalenko V. |
|
dc.contributor.author |
Krupskaya Y. |
|
dc.contributor.author |
Kataev V. |
|
dc.contributor.author |
Büchner B. |
|
dc.contributor.author |
Senkovska I. |
|
dc.contributor.author |
Kaskel S. |
|
dc.date.accessioned |
2018-09-19T21:19:25Z |
|
dc.date.available |
2018-09-19T21:19:25Z |
|
dc.date.issued |
2016 |
|
dc.identifier.issn |
1528-7483 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/143756 |
|
dc.description.abstract |
© 2016 American Chemical Society.A flexible and hydrolytically stable metal-organic framework [Mn(H2O)2(Fc(PHOO)2)·2H2O]n has been synthesized using ferrocene-based ligand bearing phosphinic groups (Fc(PHOOH)2 = 1,1′-ferrocenediyl-bis(H-phosphinic acid)). In this compound manganese atoms are bound by phosphinate fragments to give infinite chains, and the latter are interconnected by ferrocene groups to form two-dimensional coordination polymer. The elimination of both coordinated and lattice water molecules during heating up to 150 °C produced the compound, which is nonporous for nitrogen, but can selectively adsorb water over methanol and other solvents at 298 K. The reversible structural transformation during adsorption/desorption of water is also reflected in a change of magnetic properties of the metal-organic framework. |
|
dc.relation.ispartofseries |
Crystal Growth and Design |
|
dc.title |
Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)) |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
9 |
|
dc.relation.ispartofseries-volume |
16 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
5084 |
|
dc.source.id |
SCOPUS15287483-2016-16-9-SID84986184279 |
|