Показать сокращенную информацию
dc.contributor.author | Shekurov R. | |
dc.contributor.author | Miluykov V. | |
dc.contributor.author | Kataeva O. | |
dc.contributor.author | Krivolapov D. | |
dc.contributor.author | Sinyashin O. | |
dc.contributor.author | Gerasimova T. | |
dc.contributor.author | Katsyuba S. | |
dc.contributor.author | Kovalenko V. | |
dc.contributor.author | Krupskaya Y. | |
dc.contributor.author | Kataev V. | |
dc.contributor.author | Büchner B. | |
dc.contributor.author | Senkovska I. | |
dc.contributor.author | Kaskel S. | |
dc.date.accessioned | 2018-09-19T21:19:25Z | |
dc.date.available | 2018-09-19T21:19:25Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 1528-7483 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/143756 | |
dc.description.abstract | © 2016 American Chemical Society.A flexible and hydrolytically stable metal-organic framework [Mn(H2O)2(Fc(PHOO)2)·2H2O]n has been synthesized using ferrocene-based ligand bearing phosphinic groups (Fc(PHOOH)2 = 1,1′-ferrocenediyl-bis(H-phosphinic acid)). In this compound manganese atoms are bound by phosphinate fragments to give infinite chains, and the latter are interconnected by ferrocene groups to form two-dimensional coordination polymer. The elimination of both coordinated and lattice water molecules during heating up to 150 °C produced the compound, which is nonporous for nitrogen, but can selectively adsorb water over methanol and other solvents at 298 K. The reversible structural transformation during adsorption/desorption of water is also reflected in a change of magnetic properties of the metal-organic framework. | |
dc.relation.ispartofseries | Crystal Growth and Design | |
dc.title | Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)) | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 9 | |
dc.relation.ispartofseries-volume | 16 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 5084 | |
dc.source.id | SCOPUS15287483-2016-16-9-SID84986184279 |