dc.contributor.author |
Khrizanforov M. |
|
dc.contributor.author |
Fedorenko S. |
|
dc.contributor.author |
Strekalova S. |
|
dc.contributor.author |
Kholin K. |
|
dc.contributor.author |
Mustafina A. |
|
dc.contributor.author |
Zhilkin M. |
|
dc.contributor.author |
Khrizanforova V. |
|
dc.contributor.author |
Osin Y. |
|
dc.contributor.author |
Salnikov V. |
|
dc.contributor.author |
Gryaznova T. |
|
dc.contributor.author |
Budnikova Y. |
|
dc.date.accessioned |
2018-09-19T21:18:28Z |
|
dc.date.available |
2018-09-19T21:18:28Z |
|
dc.date.issued |
2016 |
|
dc.identifier.issn |
1477-9226 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/143743 |
|
dc.description.abstract |
© The Royal Society of Chemistry 2016.We have developed NiIII-doped silica nanoparticles ([(bpy)xNiIII]@SiO2) as a recyclable, low-leaching, and efficient oxidative functionalization nanocatalyst for aromatic C-H bonds. The catalyst is obtained by doping the complex [(bpy)3NiII] on silica nanoparticles along with its subsequent electrooxidation to [(bpy)xNiIII] without an additional oxidant. The coupling reaction of arenes with perfluoroheptanoic acid occurs with 100% conversion of reactants in a single step at room temperature under nanoheterogeneous conditions. The catalyst content is only 1% with respect to the substrates under electrochemical regeneration conditions. The catalyst can be easily separated from the reaction mixture and reused a minimum of five times. The results emphasize immobilization on the silica support and the electrochemical regeneration of NiIII complexes as a facile route for developing an efficient nanocatalyst for oxidative functionalization. |
|
dc.relation.ispartofseries |
Dalton Transactions |
|
dc.title |
A Ni(III) complex stabilized by silica nanoparticles as an efficient nanoheterogeneous catalyst for oxidative C-H fluoroalkylation |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
30 |
|
dc.relation.ispartofseries-volume |
45 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
11976 |
|
dc.source.id |
SCOPUS14779226-2016-45-30-SID84979919010 |
|