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dc.contributor.author | Khrizanforov M. | |
dc.contributor.author | Fedorenko S. | |
dc.contributor.author | Strekalova S. | |
dc.contributor.author | Kholin K. | |
dc.contributor.author | Mustafina A. | |
dc.contributor.author | Zhilkin M. | |
dc.contributor.author | Khrizanforova V. | |
dc.contributor.author | Osin Y. | |
dc.contributor.author | Salnikov V. | |
dc.contributor.author | Gryaznova T. | |
dc.contributor.author | Budnikova Y. | |
dc.date.accessioned | 2018-09-19T21:18:28Z | |
dc.date.available | 2018-09-19T21:18:28Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/143743 | |
dc.description.abstract | © The Royal Society of Chemistry 2016.We have developed NiIII-doped silica nanoparticles ([(bpy)xNiIII]@SiO2) as a recyclable, low-leaching, and efficient oxidative functionalization nanocatalyst for aromatic C-H bonds. The catalyst is obtained by doping the complex [(bpy)3NiII] on silica nanoparticles along with its subsequent electrooxidation to [(bpy)xNiIII] without an additional oxidant. The coupling reaction of arenes with perfluoroheptanoic acid occurs with 100% conversion of reactants in a single step at room temperature under nanoheterogeneous conditions. The catalyst content is only 1% with respect to the substrates under electrochemical regeneration conditions. The catalyst can be easily separated from the reaction mixture and reused a minimum of five times. The results emphasize immobilization on the silica support and the electrochemical regeneration of NiIII complexes as a facile route for developing an efficient nanocatalyst for oxidative functionalization. | |
dc.relation.ispartofseries | Dalton Transactions | |
dc.title | A Ni(III) complex stabilized by silica nanoparticles as an efficient nanoheterogeneous catalyst for oxidative C-H fluoroalkylation | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 30 | |
dc.relation.ispartofseries-volume | 45 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 11976 | |
dc.source.id | SCOPUS14779226-2016-45-30-SID84979919010 |