Kinetics and thermochemistry of [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene

dc.contributor.author	Kiselev V.
dc.contributor.author	Kornilov D.
dc.contributor.author	Anikin O.
dc.contributor.author	Latypova L.
dc.contributor.author	Bermeshev M.
dc.contributor.author	Chapala P.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-19T21:02:27Z
dc.date.available	2018-09-19T21:02:27Z
dc.date.issued	2016
dc.identifier.issn	1070-4280
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/143518
dc.description.abstract	© 2016, Pleiades Publishing, Ltd.Kinetic data for the unusual [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene in toluene have been obtained for the first time. The same reaction in 1,4-dioxane appears to be the most exothermic among known cycloaddition reactions. The entropy of activation and reaction volume differ only slightly from the corresponding parameters of conventional Diels–Alder reactions.
dc.relation.ispartofseries	Russian Journal of Organic Chemistry
dc.title	Kinetics and thermochemistry of [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene
dc.type	Article
dc.relation.ispartofseries-issue	6
dc.relation.ispartofseries-volume	52
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	777
dc.source.id	SCOPUS10704280-2016-52-6-SID84979284483

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.