Adsorption properties of palladium particles supported on aluminum oxides with varied acidity in hydrogenation of butadiene-1,3

dc.contributor.author	Boretskaya A.
dc.contributor.author	Il’yasov I.
dc.contributor.author	Lamberov A.
dc.contributor.author	Laskin A.
dc.date.accessioned	2018-09-19T21:02:18Z
dc.date.available	2018-09-19T21:02:18Z
dc.date.issued	2017
dc.identifier.issn	1070-4272
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/143513
dc.description.abstract	© 2017, Pleiades Publishing, Ltd.Influence exerted by acid-base modifiers of aluminum hydroxide on the texture and acid characteristics of the aluminum oxide support was studied. The effect of the modified aluminum oxides on the charge state of the active component of aluminum-palladium catalysts was determined. It was found that catalysts based on a support with high concentration of strong acid centers are characterized by low conversion of butadiene-1,3 due to the firm chemisorption of the diene on electron-deficient palladium particles. Their formation is due to the strong metal-support interaction. By contrast, catalysts synthesized with supports having a small number of acid centers provide a high conversion of butadiene-1,3.
dc.relation.ispartofseries	Russian Journal of Applied Chemistry
dc.title	Adsorption properties of palladium particles supported on aluminum oxides with varied acidity in hydrogenation of butadiene-1,3
dc.type	Article
dc.relation.ispartofseries-issue	2
dc.relation.ispartofseries-volume	90
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	161
dc.source.id	SCOPUS10704272-2017-90-2-SID85020044577

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.