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Adsorption properties of palladium particles supported on aluminum oxides with varied acidity in hydrogenation of butadiene-1,3

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dc.contributor.author Boretskaya A.
dc.contributor.author Il’yasov I.
dc.contributor.author Lamberov A.
dc.contributor.author Laskin A.
dc.date.accessioned 2018-09-19T21:02:18Z
dc.date.available 2018-09-19T21:02:18Z
dc.date.issued 2017
dc.identifier.issn 1070-4272
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/143513
dc.description.abstract © 2017, Pleiades Publishing, Ltd.Influence exerted by acid-base modifiers of aluminum hydroxide on the texture and acid characteristics of the aluminum oxide support was studied. The effect of the modified aluminum oxides on the charge state of the active component of aluminum-palladium catalysts was determined. It was found that catalysts based on a support with high concentration of strong acid centers are characterized by low conversion of butadiene-1,3 due to the firm chemisorption of the diene on electron-deficient palladium particles. Their formation is due to the strong metal-support interaction. By contrast, catalysts synthesized with supports having a small number of acid centers provide a high conversion of butadiene-1,3.
dc.relation.ispartofseries Russian Journal of Applied Chemistry
dc.title Adsorption properties of palladium particles supported on aluminum oxides with varied acidity in hydrogenation of butadiene-1,3
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 90
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 161
dc.source.id SCOPUS10704272-2017-90-2-SID85020044577


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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