dc.contributor.author |
Nemtarev A. |
|
dc.contributor.author |
Shemakhina M. |
|
dc.contributor.author |
Mironov V. |
|
dc.date.accessioned |
2018-09-19T21:00:52Z |
|
dc.date.available |
2018-09-19T21:00:52Z |
|
dc.date.issued |
2017 |
|
dc.identifier.issn |
1070-3632 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/143510 |
|
dc.description.abstract |
© 2017, Pleiades Publishing, Ltd.A convenient approach to the synthesis of 3,3,6-trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-3-ene-2-oxide was developed based on the reaction of the naturally occurring terpenoketone pulegone with methyl dichlorophosphite. Treatment of oxaphospholene-2-oxide with water or ethanol yielded γ-phosphoryl ketones, dimephosphone analogs. The studied hydrolysis and alcoholysis processes differ in stereoselectivity. |
|
dc.relation.ispartofseries |
Russian Journal of General Chemistry |
|
dc.subject |
methyl dichlorophosphite |
|
dc.subject |
oxaphospholene |
|
dc.subject |
oxoalkylphosphonates |
|
dc.subject |
phosphoryl ketones |
|
dc.subject |
phosphorylation |
|
dc.subject |
pulegone |
|
dc.title |
3,3,6-Trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-4-ene-2-oxide as a convenient precursor for the synthesis of dimephosphone analogs |
|
dc.type |
Letter |
|
dc.relation.ispartofseries-issue |
4 |
|
dc.relation.ispartofseries-volume |
87 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
887 |
|
dc.source.id |
SCOPUS10703632-2017-87-4-SID85019644779 |
|