3,3,6-Trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-4-ene-2-oxide as a convenient precursor for the synthesis of dimephosphone analogs

dc.contributor.author	Nemtarev A.
dc.contributor.author	Shemakhina M.
dc.contributor.author	Mironov V.
dc.date.accessioned	2018-09-19T21:00:52Z
dc.date.available	2018-09-19T21:00:52Z
dc.date.issued	2017
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/143510
dc.description.abstract	© 2017, Pleiades Publishing, Ltd.A convenient approach to the synthesis of 3,3,6-trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-3-ene-2-oxide was developed based on the reaction of the naturally occurring terpenoketone pulegone with methyl dichlorophosphite. Treatment of oxaphospholene-2-oxide with water or ethanol yielded γ-phosphoryl ketones, dimephosphone analogs. The studied hydrolysis and alcoholysis processes differ in stereoselectivity.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.subject	methyl dichlorophosphite
dc.subject	oxaphospholene
dc.subject	oxoalkylphosphonates
dc.subject	phosphoryl ketones
dc.subject	phosphorylation
dc.subject	pulegone
dc.title	3,3,6-Trimethyl-2-chlorocyclohexeno[1,2-d]-1,2-oxaphosphol-4-ene-2-oxide as a convenient precursor for the synthesis of dimephosphone analogs
dc.type	Letter
dc.relation.ispartofseries-issue	4
dc.relation.ispartofseries-volume	87
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	887
dc.source.id	SCOPUS10703632-2017-87-4-SID85019644779

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Публикации сотрудников КФУ Scopus [24551]
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