Показать сокращенную информацию
dc.contributor.author | Ivanova T. | |
dc.contributor.author | Mingalieva L. | |
dc.contributor.author | Ovchinnikov I. | |
dc.contributor.author | Turanova O. | |
dc.contributor.author | Ivanova G. | |
dc.contributor.author | Gilmutdinov I. | |
dc.date.accessioned | 2018-09-19T21:00:33Z | |
dc.date.available | 2018-09-19T21:00:33Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/143506 | |
dc.description.abstract | © 2016, Pleiades Publishing, Ltd.[FeLX2]Y [L = N,N'-ethylenebis(salicylimine) (salen), N,N'-ethylenebis(acetylacetonylimine) (acen), or N,N'-ethylenebis(3-methyloxysalicylimine) (vanen); X = imidazole or N-methylimidazole; Y = BF4, ClO4, or BPh4] compounds have been prepared and studied by means of EPR and magnetic susceptibility measurements at 5–300 K. It has been shown that the different electron-donating properties of acen and salen planar ligands result in different spin states of Fe(III) ions. Intermolecular π-interactions of the outer-sphere BPh4 ion affect the complexes spin state as well. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.subject | EPR spectroscopy | |
dc.subject | Fe(III) complex | |
dc.subject | magnetic susceptibility | |
dc.subject | variable spin properties | |
dc.title | Lability of spin state of Fe(III) complexes with tetradentate Schiff’s bases | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 7 | |
dc.relation.ispartofseries-volume | 86 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1647 | |
dc.source.id | SCOPUS10703632-2016-86-7-SID84983036017 |