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Lability of spin state of Fe(III) complexes with tetradentate Schiff’s bases

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dc.contributor.author Ivanova T.
dc.contributor.author Mingalieva L.
dc.contributor.author Ovchinnikov I.
dc.contributor.author Turanova O.
dc.contributor.author Ivanova G.
dc.contributor.author Gilmutdinov I.
dc.date.accessioned 2018-09-19T21:00:33Z
dc.date.available 2018-09-19T21:00:33Z
dc.date.issued 2016
dc.identifier.issn 1070-3632
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/143506
dc.description.abstract © 2016, Pleiades Publishing, Ltd.[FeLX2]Y [L = N,N'-ethylenebis(salicylimine) (salen), N,N'-ethylenebis(acetylacetonylimine) (acen), or N,N'-ethylenebis(3-methyloxysalicylimine) (vanen); X = imidazole or N-methylimidazole; Y = BF4, ClO4, or BPh4] compounds have been prepared and studied by means of EPR and magnetic susceptibility measurements at 5–300 K. It has been shown that the different electron-donating properties of acen and salen planar ligands result in different spin states of Fe(III) ions. Intermolecular π-interactions of the outer-sphere BPh4 ion affect the complexes spin state as well.
dc.relation.ispartofseries Russian Journal of General Chemistry
dc.subject EPR spectroscopy
dc.subject Fe(III) complex
dc.subject magnetic susceptibility
dc.subject variable spin properties
dc.title Lability of spin state of Fe(III) complexes with tetradentate Schiff’s bases
dc.type Article
dc.relation.ispartofseries-issue 7
dc.relation.ispartofseries-volume 86
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1647
dc.source.id SCOPUS10703632-2016-86-7-SID84983036017


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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