dc.contributor.author |
Ivanova T. |
|
dc.contributor.author |
Ovchinnikov I. |
|
dc.contributor.author |
Gil’mutdinov I. |
|
dc.contributor.author |
Mingalieva L. |
|
dc.contributor.author |
Turanova O. |
|
dc.contributor.author |
Ivanova G. |
|
dc.date.accessioned |
2018-09-19T20:52:36Z |
|
dc.date.available |
2018-09-19T20:52:36Z |
|
dc.date.issued |
2016 |
|
dc.identifier.issn |
1063-7834 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/143369 |
|
dc.description.abstract |
© 2016, Pleiades Publishing, Ltd. The [Fe(acen)pic2]BPh4 · nH2O compound has been synthesized and studied in the temperature interval of 5–300 K by the methods of EPR and magnetic susceptibility. The existence of ferromagnetic interactions between Fe(III) complexes in this compound has been revealed, in contrast to unhydrated [Fe(acen)pic2]BPh4. The reduction in the integrated intensity of the magnetic resonance signal as the temperature decreases below 80 K has been explained by the transition of high-spin ions to the low-spin state. It has been shown that the phase transition temperature in the presence of intermolecular (ferromagnetic) interactions is lower than that in the case of noninteracting centers. |
|
dc.relation.ispartofseries |
Physics of the Solid State |
|
dc.title |
Specific features of spin-variable properties of [Fe(acen)pic2]BPh4 · nH2O |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
2 |
|
dc.relation.ispartofseries-volume |
58 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
280 |
|
dc.source.id |
SCOPUS10637834-2016-58-2-SID84958559560 |
|