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Specific features of spin-variable properties of [Fe(acen)pic2]BPh4 · nH2O

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dc.contributor.author Ivanova T.
dc.contributor.author Ovchinnikov I.
dc.contributor.author Gil’mutdinov I.
dc.contributor.author Mingalieva L.
dc.contributor.author Turanova O.
dc.contributor.author Ivanova G.
dc.date.accessioned 2018-09-19T20:52:36Z
dc.date.available 2018-09-19T20:52:36Z
dc.date.issued 2016
dc.identifier.issn 1063-7834
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/143369
dc.description.abstract © 2016, Pleiades Publishing, Ltd. The [Fe(acen)pic2]BPh4 · nH2O compound has been synthesized and studied in the temperature interval of 5–300 K by the methods of EPR and magnetic susceptibility. The existence of ferromagnetic interactions between Fe(III) complexes in this compound has been revealed, in contrast to unhydrated [Fe(acen)pic2]BPh4. The reduction in the integrated intensity of the magnetic resonance signal as the temperature decreases below 80 K has been explained by the transition of high-spin ions to the low-spin state. It has been shown that the phase transition temperature in the presence of intermolecular (ferromagnetic) interactions is lower than that in the case of noninteracting centers.
dc.relation.ispartofseries Physics of the Solid State
dc.title Specific features of spin-variable properties of [Fe(acen)pic2]BPh4 · nH2O
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 58
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 280
dc.source.id SCOPUS10637834-2016-58-2-SID84958559560


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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