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dc.contributor.author | Maltceva O. | |
dc.contributor.author | Mamardashvili G. | |
dc.contributor.author | Khodov I. | |
dc.contributor.author | Lazovskiy D. | |
dc.contributor.author | Khodova V. | |
dc.contributor.author | Krest’yaninov M. | |
dc.contributor.author | Mamardashvili N. | |
dc.contributor.author | Dehaen W. | |
dc.date.accessioned | 2018-09-19T20:49:52Z | |
dc.date.available | 2018-09-19T20:49:52Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1061-0278 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/143320 | |
dc.description.abstract | © 2016 Informa UK Limited, trading as Taylor & Francis Group.By means of spectrophotometric titration and 1H NMR spectroscopy, the selective binding ability of the Zn-5,15-bis-(2,6-dodecyloxyphenyl)porphyrin towards nitrogen containing organic molecules of various nature has been studied. It has been found that the presence of long alkoxy substituents at the ortho-positions of the Zn-porphyrin phenyl rings prevents the axial coordination of tertiary amines and, conversely, creates favourable conditions for binding of a primary diamine due to the presence of additional binding sites, namely the oxygen atoms of the ortho–ortho′- dodecyloxy substituents of the meso phenyl groups. The formation of stable complexes with multiple binding sites has been confirmed by DFT quantum chemical calculations and two-dimensional NMR experiments. | |
dc.relation.ispartofseries | Supramolecular Chemistry | |
dc.subject | binding ability | |
dc.subject | Porphyrin | |
dc.subject | receptor | |
dc.subject | sensing device | |
dc.subject | spectrophotometric titration | |
dc.title | Molecular recognition of nitrogen–containing bases by Zn[5,15-bis-(2,6-dodecyloxyphenyl)]porphyrin | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 5 | |
dc.relation.ispartofseries-volume | 29 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 360 | |
dc.source.id | SCOPUS10610278-2017-29-5-SID84990973232 |