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Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes

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dc.contributor.author Muravev A.
dc.contributor.author Galieva F.
dc.contributor.author Bazanova O.
dc.contributor.author Sharafutdinova D.
dc.contributor.author Solovieva S.
dc.contributor.author Antipin I.
dc.contributor.author Konovalov A.
dc.date.accessioned 2018-09-19T20:49:47Z
dc.date.available 2018-09-19T20:49:47Z
dc.date.issued 2016
dc.identifier.issn 1061-0278
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/143317
dc.description.abstract © 2016 © 2016 A.E. Arbuzov Institute of Organic and Physical Chemistry.The synthesis and structure of thiacalix[4]monocrowns in 1,3-alternate configuration substituted by terpyridyl fragments on the lower rim are being discussed. It has been shown that the number of oxyethylene units in oligoethylene glycol chain affects the distribution of the yields of the cross-linking products leading to either thiacalix[4]monocrowns or bisthiacalix[4]arenes. Their complexation ability towards alkali metal and lanthanide ions has been studied using liquid extraction and MALDI TOF MS, in addition to luminescent properties of ligands and their lanthanide complexes. The NMR titration data discovered the participation of both crown ether and terpyridyl fragment in the coordination of lanthanide cations. The fluorescent titration showed the nonlinear emission response to the amount of lanthanide ions.
dc.relation.ispartofseries Supramolecular Chemistry
dc.subject lanthanides
dc.subject luminescence
dc.subject terpyridines
dc.subject Thiacalix[4]monocrowns
dc.title Thiacalix[4]monocrowns with terpyridine functional groups as new structural units for luminescent polynuclear lanthanide complexes
dc.type Article
dc.relation.ispartofseries-issue 5-6
dc.relation.ispartofseries-volume 28
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 589
dc.source.id SCOPUS10610278-2016-28-56-SID84961215223


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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