dc.contributor.author |
Plotnikova A. |
|
dc.contributor.author |
Kuramshin A. |
|
dc.contributor.author |
Galkin V. |
|
dc.date.accessioned |
2018-09-19T20:48:50Z |
|
dc.date.available |
2018-09-19T20:48:50Z |
|
dc.date.issued |
2016 |
|
dc.identifier.issn |
1042-6507 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/143301 |
|
dc.description.abstract |
© 2016 Taylor & Francis Group, LLC.We have revealed that the reaction of hexacarbonylmetal(0) with the dimethylphosphite can afford the organometallic species having the hydroxyl-tautomeric form of the H-phosphonate in the metals’ coordination sphere. Theoretical and experimental investigations reveal the strong acidity of these organometallic compounds aswell as their possibility to take part in electrophilic hydrophosphorylation of inactivated C=C and C≡C bonds. |
|
dc.relation.ispartofseries |
Phosphorus, Sulfur and Silicon and the Related Elements |
|
dc.subject |
acidity |
|
dc.subject |
chromium group complexes |
|
dc.subject |
Dimethylphosphite |
|
dc.subject |
hydroxy-tautomeric form |
|
dc.title |
The acidity of the hydroxy-tautomeric form of dimethylphosphite stabilized with chromium group metals |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
11-12 |
|
dc.relation.ispartofseries-volume |
191 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1568 |
|
dc.source.id |
SCOPUS10426507-2016-191-1112-SID84992665986 |
|