The acidity of the hydroxy-tautomeric form of dimethylphosphite stabilized with chromium group metals

dc.contributor.author	Plotnikova A.
dc.contributor.author	Kuramshin A.
dc.contributor.author	Galkin V.
dc.date.accessioned	2018-09-19T20:48:50Z
dc.date.available	2018-09-19T20:48:50Z
dc.date.issued	2016
dc.identifier.issn	1042-6507
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/143301
dc.description.abstract	© 2016 Taylor & Francis Group, LLC.We have revealed that the reaction of hexacarbonylmetal(0) with the dimethylphosphite can afford the organometallic species having the hydroxyl-tautomeric form of the H-phosphonate in the metals’ coordination sphere. Theoretical and experimental investigations reveal the strong acidity of these organometallic compounds aswell as their possibility to take part in electrophilic hydrophosphorylation of inactivated C=C and C≡C bonds.
dc.relation.ispartofseries	Phosphorus, Sulfur and Silicon and the Related Elements
dc.subject	acidity
dc.subject	chromium group complexes
dc.subject	Dimethylphosphite
dc.subject	hydroxy-tautomeric form
dc.title	The acidity of the hydroxy-tautomeric form of dimethylphosphite stabilized with chromium group metals
dc.type	Article
dc.relation.ispartofseries-issue	11-12
dc.relation.ispartofseries-volume	191
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1568
dc.source.id	SCOPUS10426507-2016-191-1112-SID84992665986

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Публикации сотрудников КФУ Scopus [24551]
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