Электронный архив
Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones
- Главная
- →
- Научные публикации в Scopus
- →
- Публикации сотрудников КФУ Scopus
- →
- Просмотр элемента
JavaScript is disabled for your browser. Some features of this site may not work without it.
Показать сокращенную информацию
| dc.contributor.author | Gorbachuk E. | |
| dc.contributor.author | Badeeva E. | |
| dc.contributor.author | Katsyuba S. | |
| dc.contributor.author | Pavlov P. | |
| dc.contributor.author | Khayarov K. | |
| dc.contributor.author | Sinyashin O. | |
| dc.contributor.author | Yakhvarov D. | |
| dc.date.accessioned | 2018-09-19T20:48:36Z | |
| dc.date.available | 2018-09-19T20:48:36Z | |
| dc.date.issued | 2016 | |
| dc.identifier.issn | 1042-6507 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/143293 | |
| dc.description.abstract | © 2016 Taylor & Francis Group, LLC.We present the study of reactivity of electrochemically generated in situ from white phosphorus P4 phosphine oxide H3PO toward various ketones (acetone, methylethylketone, methyl-n-propylketone). This interaction was found to give a selective formation of mono- and bis-(α-oxyalkyl)phosphine oxides RRʹC(OH)P(O)H2 (1) and (RRʹC(OH))2P(O)H (2) where R = Me; Rʹ = Me, Et, n-Pr. Thermal properties of the formed primary and secondary phosphine oxides have been studied and quantum chemical calculations of thermodynamic stability of these compounds were performed. | |
| dc.relation.ispartofseries | Phosphorus, Sulfur and Silicon and the Related Elements | |
| dc.subject | DFT calculations | |
| dc.subject | Electrochemistry | |
| dc.subject | ketones | |
| dc.subject | phosphine oxide | |
| dc.subject | white phosphorus | |
| dc.title | Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 11-12 | |
| dc.relation.ispartofseries-volume | 191 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 1480 | |
| dc.source.id | SCOPUS10426507-2016-191-1112-SID84992645548 |
Файлы в этом документе
Данный элемент включен в следующие коллекции
-
Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.