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Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones

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dc.contributor.author Gorbachuk E.
dc.contributor.author Badeeva E.
dc.contributor.author Katsyuba S.
dc.contributor.author Pavlov P.
dc.contributor.author Khayarov K.
dc.contributor.author Sinyashin O.
dc.contributor.author Yakhvarov D.
dc.date.accessioned 2018-09-19T20:48:36Z
dc.date.available 2018-09-19T20:48:36Z
dc.date.issued 2016
dc.identifier.issn 1042-6507
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/143293
dc.description.abstract © 2016 Taylor & Francis Group, LLC.We present the study of reactivity of electrochemically generated in situ from white phosphorus P4 phosphine oxide H3PO toward various ketones (acetone, methylethylketone, methyl-n-propylketone). This interaction was found to give a selective formation of mono- and bis-(α-oxyalkyl)phosphine oxides RRʹC(OH)P(O)H2 (1) and (RRʹC(OH))2P(O)H (2) where R = Me; Rʹ = Me, Et, n-Pr. Thermal properties of the formed primary and secondary phosphine oxides have been studied and quantum chemical calculations of thermodynamic stability of these compounds were performed.
dc.relation.ispartofseries Phosphorus, Sulfur and Silicon and the Related Elements
dc.subject DFT calculations
dc.subject Electrochemistry
dc.subject ketones
dc.subject phosphine oxide
dc.subject white phosphorus
dc.title Thermal stability of primary and secondary phosphine oxides formed as a reaction of phosphine oxide with ketones
dc.type Article
dc.relation.ispartofseries-issue 11-12
dc.relation.ispartofseries-volume 191
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1480
dc.source.id SCOPUS10426507-2016-191-1112-SID84992645548


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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