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Thermodynamic properties of methylprednisolone aceponate

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dc.contributor.author Knyazev A.
dc.contributor.author Emel'yanenko V.
dc.contributor.author Smirnova N.
dc.contributor.author Stepanova O.
dc.contributor.author Shipilova A.
dc.contributor.author Markin A.
dc.contributor.author Samosudova Y.
dc.contributor.author Gusarova E.
dc.contributor.author Knyazeva S.
dc.contributor.author Verevkin S.
dc.date.accessioned 2018-09-19T20:14:44Z
dc.date.available 2018-09-19T20:14:44Z
dc.date.issued 2016
dc.identifier.issn 0021-9614
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/142729
dc.description.abstract © 2016 Elsevier LtdIn the present work, temperature dependence of heat capacity of methylprednisolone aceponate has been measured for the first time over the range from 7 K to 346 K by precision adiabatic vacuum calorimetry. Based on the experimental results, the thermodynamic functions of the methylprednisolone aceponate, namely, the heat capacity, enthalpy H°(T)−H°(0), entropy S°(T)−S°(0) and Gibbs function G°(T)−H°(0) have been determined for the range from T/K → 0–333. The enthalpy of combustion (−14304.4 ± 9.1) kJ·mol−1 of the methylprednisolone aceponate was determined for the first time using high-precision combustion calorimeter. The standard molar enthalpy of formation in the crystalline state (−1465.3 ± 9.8) kJ·mol−1 of compound at 298.15 K was derived from the combustion experiments. Using a combination of the adiabatic and combustion calorimetry results the thermodynamic functions of formation of the folic acid dihydrate at T = 298.15 K and p = 0.1 MPa have been calculated.
dc.relation.ispartofseries Journal of Chemical Thermodynamics
dc.subject Adiabatic vacuum calorimetry
dc.subject Combustion calorimetry
dc.subject Heat capacity
dc.subject Methylprednisolone aceponate
dc.subject Steroid hormone
dc.subject Thermodynamic functions
dc.title Thermodynamic properties of methylprednisolone aceponate
dc.type Article
dc.relation.ispartofseries-volume 103
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 244
dc.source.id SCOPUS00219614-2016-103-SID84983035832


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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