dc.contributor.author |
Emel'Yanenko V. |
|
dc.contributor.author |
Nagrimanov R. |
|
dc.contributor.author |
Solomonov B. |
|
dc.contributor.author |
Verevkin S. |
|
dc.date.accessioned |
2018-09-19T20:14:40Z |
|
dc.date.available |
2018-09-19T20:14:40Z |
|
dc.date.issued |
2016 |
|
dc.identifier.issn |
0021-9614 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/142727 |
|
dc.description.abstract |
© 2016 Elsevier Ltd.Standard molar enthalpies of formation of 2-adamantanone and 1-adamantanol were measured by using high-precision combustion calorimetry. Vapour pressures of 2-adamantanone, 1-acetyl-adamantane, 1- and 2-carboxy-adamantanes were measured by using the transpiration method. Standard molar enthalpies of sublimation of this substituted adamantanes at 298.15 K were derived from vapour pressure temperature dependences. The standard molar enthalpy of solution of 1-acetyl-adamantane in cyclohexane was measured with the high-precision solution calorimetry. An empirical procedure based on the solution calorimetry was developed to derive sublimation enthalpies of substituted adamantanes independently. Molar enthalpies of fusion of 1-acetyl-adamantane, 1- and 2-carboxy-adamantanes were measured with help of DSC. Thermochemical data on oxygen containing adamantane derivatives were collected and evaluated. Gas-phase enthalpies of formation calculated with the high-level quantum-chemical method G3MP2 and compared with the experimental results. The consistent data set of the benchmark quality is suggested for practical thermochemical calculations. |
|
dc.relation.ispartofseries |
Journal of Chemical Thermodynamics |
|
dc.subject |
Adamantane derivatives |
|
dc.subject |
Combustion calorimetry |
|
dc.subject |
Enthalpies of phase transitions |
|
dc.subject |
Solution calorimetry |
|
dc.subject |
Transpiration method |
|
dc.subject |
Vapour pressure |
|
dc.title |
Adamantanes: Benchmarking of thermochemical properties |
|
dc.type |
Article |
|
dc.relation.ispartofseries-volume |
101 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
130 |
|
dc.source.id |
SCOPUS00219614-2016-101-SID84971405804 |
|