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dc.contributor.author | Luconi L. | |
dc.contributor.author | Gafurov Z. | |
dc.contributor.author | Rossin A. | |
dc.contributor.author | Tuci G. | |
dc.contributor.author | Sinyashin O. | |
dc.contributor.author | Yakhvarov D. | |
dc.contributor.author | Giambastiani G. | |
dc.date.accessioned | 2018-09-19T20:12:05Z | |
dc.date.available | 2018-09-19T20:12:05Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/142680 | |
dc.description.abstract | © 2017 Elsevier B.V.Cationic palladium complexes stabilized by a tridentate neutral (N,N,C) ligand containing a sterically hindered N-heterocyclic carbene (NHC) moiety have been prepared and characterized. The nature of the anionic counterion in the palladium complex has been varied to get crystals suitable for X-ray diffraction. The square planar structure of one of these complexes along with the axial contribution of the sterically hindered NHC fragment has been confirmed by X-ray analysis. In addition, all the isolated [(κ3-N,N,C)PdIICl]+X- [X- =Cl, PF6, BF4, B(C6H3Cl2)4] ion pairs have been scrutinized as catalysts in the cross-coupling Suzuki-Miyaura reaction between phenylboronic acid and variably substituted halo-aryl acceptors. Selected issues from this series have shown improved catalyst turn-over frequencies (TOFs) with respect to structurally related catalytic systems of the state-of-the-art. | |
dc.relation.ispartofseries | Inorganica Chimica Acta | |
dc.subject | NHC-containing ligand | |
dc.subject | Palladium complexes | |
dc.subject | Suzuki-Miyaura coupling | |
dc.title | Palladium(II) pyrazolyl-pyridyl complexes containing a sterically hindered N-heterocyclic carbene moiety for the Suzuki-Miyaura cross-coupling reaction | |
dc.type | Article in Press | |
dc.collection | Публикации сотрудников КФУ | |
dc.source.id | SCOPUS00201693-2017-SID85015998883 |