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Hyperbranched polyester poly(3-diethylaminepropionate)s and their copper(II) complexes: Synthesis, characterization and biological investigation

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dc.contributor.author Kutyreva M.
dc.contributor.author Gataulina A.
dc.contributor.author Kutyrev G.
dc.contributor.author Ulakhovich N.
dc.contributor.author Newman T.
dc.contributor.author Khasanova E.
dc.contributor.author Bondar O.
dc.contributor.author Yurtaeva S.
dc.contributor.author Ziganshina S.
dc.contributor.author Khaldeeva E.
dc.date.accessioned 2018-09-19T20:11:58Z
dc.date.available 2018-09-19T20:11:58Z
dc.date.issued 2016
dc.identifier.issn 0020-1693
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/142676
dc.description.abstract © 2016 Elsevier B.V. All rights reserved.New polydentate ligands based on hyperbranched second and third generation polyesters containing terminal (3-diethylamino)propionate fragments and their polynuclear copper(II) complexes were synthesized and characterized by spectroscopic methods. The acid-base properties spectroscopy determined that the functionalization degree of the diethylamine-modified hyperbranched polyesters (LI, LII) increases from the second (56%) to third (81%) generation. The polynuclear complexes Cu(II)-LI and Cu(II)-LII were observed. A coordination site of the complexes contains paramagnetic fragment CuN2O2Solv2 where Solv is H2O or DMSO. The hyperbranched poly(ester amine) of the third generation have strong antifungal activity against Aspergillus fumigatus culture, and its metal complex is active against Candida albicans culture.
dc.relation.ispartofseries Inorganica Chimica Acta
dc.subject Biological activity
dc.subject Cu(II) complex
dc.subject EPR spectra
dc.subject Hyperbranched polyesters
dc.subject Ionization
dc.subject Poly-3-diethylaminepropionates
dc.title Hyperbranched polyester poly(3-diethylaminepropionate)s and their copper(II) complexes: Synthesis, characterization and biological investigation
dc.type Article
dc.relation.ispartofseries-volume 450
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 101
dc.source.id SCOPUS00201693-2016-450-SID84971280764


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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