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dc.contributor.author | Galyaltdinov S. | |
dc.contributor.author | Ziganshin M. | |
dc.contributor.author | Gubaidullin A. | |
dc.contributor.author | Vyshnevsky S. | |
dc.contributor.author | Kalchenko O. | |
dc.contributor.author | Gorbatchuk V. | |
dc.date.accessioned | 2018-09-18T20:35:57Z | |
dc.date.available | 2018-09-18T20:35:57Z | |
dc.date.issued | 2014 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/141547 | |
dc.description.abstract | An unusual bell-like relationship between guest size parameter and properties of thiacalix[4]arene (1) clathrates was observed, which is a source of their very high thermal stability. For this, calixarene 1 clathrates were prepared in a binary 'solid host-guest vapor' system and by solid-phase exchange with guests of various molecular structure. The clathrates were studied by thermal analysis and X-ray powder diffractometry. Calixarene 1 was found to have a specific anti-sieve effect excluding smaller guest compounds, while having a preference for larger compounds. This effect may be avoided using solid-phase guest exchange in clathrate preparation, but it contributes greatly to the thermal stability of exchange products. This journal is © the Partner Organisations 2014. | |
dc.title | Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 18 | |
dc.relation.ispartofseries-volume | 16 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 3781 | |
dc.source.id | SCOPUS-2014-16-18-SID84898036147 |