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Template synthesis of tetrakis-triazolylthiacalix[4]arene in the cone conformation and supramolecular structure of its hexanuclear complex with Ag(I)

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dc.contributor.author Ovsyannikov A.
dc.contributor.author Epifanova N.
dc.contributor.author Popova E.
dc.contributor.author Kyritsakas N.
dc.contributor.author Ferlay S.
dc.contributor.author Hosseini M.
dc.contributor.author Latypov S.
dc.contributor.author Soloviev S.
dc.contributor.author Antipin I.
dc.contributor.author Konovalov A.
dc.date.accessioned 2018-09-18T20:35:05Z
dc.date.available 2018-09-18T20:35:05Z
dc.date.issued 2014
dc.identifier.issn 1998-9539
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/141383
dc.description.abstract A stereoselective synthesis of the cone stereoisomer of thiacalix[4]arene bearing four triazolyl coordinating sites at the lower rim, 2, has been achieved by the 1,3-dipolar cycloaddition of p-nitrophenylazide to tetrakis-(propargyloxy) thiacalix[4]arene, 1, in presence of copper(I) iodide. A combination of 2 with AgNO3 leads to the formation of hexanuclear silver(I) complex with M:L ratio of 6:2. The latter forms a 3D π-bonded molecular network in the crystalline phase. © ISUCT Publishing.
dc.relation.ispartofseries Macroheterocycles
dc.subject 1,2,3-triazole
dc.subject 1,3-dipolar cycloaddition reaction
dc.subject Template synthesis
dc.subject Thiacalix[4]arenes
dc.title Template synthesis of tetrakis-triazolylthiacalix[4]arene in the cone conformation and supramolecular structure of its hexanuclear complex with Ag(I)
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 7
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 189
dc.source.id SCOPUS19989539-2014-7-2-SID84922833428


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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