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dc.contributor.author | Butman M. | |
dc.contributor.author | Belozerov A. | |
dc.contributor.author | Karasev N. | |
dc.contributor.author | Kochkina N. | |
dc.contributor.author | Khodov I. | |
dc.contributor.author | Ovchinnikov N. | |
dc.date.accessioned | 2018-09-18T20:34:23Z | |
dc.date.available | 2018-09-18T20:34:23Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 1995-0780 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/141269 | |
dc.description.abstract | © 2015, Pleiades Publishing, Ltd. The possibility of adjusting the separation of silicate layers in montmorillonite in a broad range of basal distances d001 (1.3–2.4 nm) at the intercalation of large (0.7–1.8 nm) polyhydroxocomplexes of aluminum ([Al13O4(OH)24(H2O)12]7+, [Al30O8(OH)56(H2O)24]18+) and aluminum/cerium synthesized through the combined hydrolysis of aluminum and cerium salts in a reactor under pressure is shown. The formation of polyhydroxocomplexes was controlled by the methods of 27Al NMR and photon correlation and fluorescent spectroscopy at different concentrations of Al3+ ions (2.5–5.1 M) in solution. Textural properties (specific surface area, total pore volume, and mesoporosity) and fractal dimensionality of the samples of intercalated montmorillonite obtained by annealing at 300°C have been determined using the method of low-temperature nitrogen adsorption–desorption. | |
dc.relation.ispartofseries | Nanotechnologies in Russia | |
dc.title | Structural and textural properties of pillared montmorillonite at intercalation of large Al- and Al/Ce-polyhydroxocomplexes | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 9-10 | |
dc.relation.ispartofseries-volume | 10 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 706 | |
dc.source.id | SCOPUS19950780-2015-10-9-10-SID84945179870 |