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Calorimetric study of solvation of low polar solutes in propylene glycol and methyl cellosolve at 298 K

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dc.contributor.author Sedov I.
dc.contributor.author Stolov M.
dc.contributor.author Solomonov B.
dc.date.accessioned 2018-09-18T20:32:10Z
dc.date.available 2018-09-18T20:32:10Z
dc.date.issued 2014
dc.identifier.issn 0040-6031
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/140891
dc.description.abstract Enthalpies of solution of low-polar substances: aliphatic and aromatic hydrocarbons, including alkanes, cycloalkanes, alkylbenzenes, and halobenzenes in two solvents, propylene glycol and methyl cellosolve, were measured at temperature T = 298.15 K using titration calorimetry. In addition, the enthalpies of solution of poorly soluble solid solutes, naphthalene and biphenyl, in these solvents were determined using indirect method by measuring the enthalpies of solution of liquid mixtures containing them. The enthalpies of solvation from the gas phase were calculated from these data. The enthalpies of solvation in propylene glycol and methyl cellosolve and previously reported enthalpies of solvation in ethylene glycol were correlated with each other and with molecular parameters of solutes. © 2014 Elsevier B.V.
dc.relation.ispartofseries Thermochimica Acta
dc.subject Enthalpy of solution
dc.subject Ethylene glycol
dc.subject Methyl cellosolve
dc.subject Propylene glycol
dc.subject Solution calorimetry
dc.subject Solvation
dc.title Calorimetric study of solvation of low polar solutes in propylene glycol and methyl cellosolve at 298 K
dc.type Article
dc.relation.ispartofseries-volume 589
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 247
dc.source.id SCOPUS00406031-2014-589-SID84902526696


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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