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Calorimetric determination of the enthalpy of specific interaction of chloroform with a number of proton-acceptor compounds

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dc.contributor.author Novikov V.
dc.contributor.author Abaidullina D.
dc.contributor.author Gainutdinova N.
dc.contributor.author Varfalomeev M.
dc.contributor.author Solomonov B.
dc.date.accessioned 2018-09-18T20:31:24Z
dc.date.available 2018-09-18T20:31:24Z
dc.date.issued 2006
dc.identifier.issn 0036-0244
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/140753
dc.description.abstract Calorimetry was used to measure the enthalpies of solution of chloroform in various proton-acceptor solvents and, vice versa, proton-acceptors in chloroform. Based on a previously proposed equation, the enthalpies of specific interaction were calculated and compared with the published data on the enthalpy of hydrogen bonding of chloroform with various proton-acceptor solvents. The composition of the H-bonded complexes mainly formed during the dissolution of proton-acceptor solutes in chloroform was established. It was demonstrated that the dissolution of ethers in chloroform is predominantly accompanied by the formation of 1: 1 complexes, while the dissolution of acetone, dimethylformamide, and dimethyl sulfoxide in chloroform gives rise to more complex associates. © Nauka/Interperiodica 2006.
dc.relation.ispartofseries Russian Journal of Physical Chemistry A
dc.title Calorimetric determination of the enthalpy of specific interaction of chloroform with a number of proton-acceptor compounds
dc.type Conference Paper
dc.relation.ispartofseries-issue 11
dc.relation.ispartofseries-volume 80
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1790
dc.source.id SCOPUS00360244-2006-80-11-SID33750357784


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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