Formation of a polynuclear cobalt(II) complex on a polydentate nanoplatform of carboxylated boltorn H20

dc.contributor.author	Kutyreva M.
dc.contributor.author	Ulakhovich N.
dc.contributor.author	Karataeva F.
dc.contributor.author	Rezepova M.
dc.contributor.author	Kutyrev G.
dc.date.accessioned	2018-09-18T20:31:22Z
dc.date.available	2018-09-18T20:31:22Z
dc.date.issued	2012
dc.identifier.issn	0036-0236
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/140750
dc.description.abstract	A method of synthesis of a polynuclear cobalt(II) complex with carboxylated Boltorn H20, a hyperbranched polyol of second generation, has been suggested. The logarithm of stability constant and the composition of the complex species BH20(OC(O)CH 2CH 2COO) 12Co 12 in a 50% acetone solution have been calculated from the electronic absorption spectra: logβ = 13.7 ± 0.2 and the composition M : L = 12 : 1. The IR spectroscopy and NMR ( 13C and 1H) point to the coordination of Co(II) ions not only at the surface of the molecule but also near its core. © Pleiades Publishing, Ltd., 2012.
dc.relation.ispartofseries	Russian Journal of Inorganic Chemistry
dc.title	Formation of a polynuclear cobalt(II) complex on a polydentate nanoplatform of carboxylated boltorn H20
dc.type	Article
dc.relation.ispartofseries-issue	9
dc.relation.ispartofseries-volume	57
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1244
dc.source.id	SCOPUS00360236-2012-57-9-SID84869019838

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