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dc.contributor.author | Kiselev V. | |
dc.contributor.author | Bolotov A. | |
dc.contributor.author | Satonin A. | |
dc.contributor.author | Shakirova I. | |
dc.contributor.author | Kashaeva H. | |
dc.contributor.author | Konovalov A. | |
dc.date.accessioned | 2018-09-18T20:23:00Z | |
dc.date.available | 2018-09-18T20:23:00Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 1520-6106 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/139309 | |
dc.description.abstract | Weight analysis of the liquid introduced into the stainless steel bomb under pressures up to 1 kbar in the temperature range of 20-50°C at the interval of 10°C was performed for 1,4-dioxane, acetonitrile, toluene, ethyl acetate, chlorobenzene, and n-hexane. The coefficients of the Tait equation were determined for all of the solvents at each temperature. There was a clear linear relation between the tangent bulk modulus (1/βT) at atmospheric pressure (1 bar) and the secant bulk modulus at 1 kbar; 1/βT = 0.9865 × (1000 V0/ΔV 1kbar) - 4559 was found at a wide range of temperatures for different liquids, including glycerol and even mercury. This represents the rule of noncrossing P-V curvatures for the liquids. Using the correlation, it is possible to predict the coefficients (C, B) of the Tait equation from the experimental data of βT at 1 bar or, on the other hand, to calculate the value of βT from experimental compression at high pressures. © 2008 American Chemical Society. | |
dc.relation.ispartofseries | Journal of Physical Chemistry B | |
dc.title | Compressibility of liquids. Rule of noncrossing V-P curvatures | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 21 | |
dc.relation.ispartofseries-volume | 112 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 6674 | |
dc.source.id | SCOPUS15206106-2008-112-21-SID53349142368 |