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Complexes of N-thiophosphorylthioureas (HL) with copper(I). Crystal structures of [Cu3L3] and [Cu(PPh3) 2L] chelates

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dc.contributor.author Sokolov F.
dc.contributor.author Babashkina M.
dc.contributor.author Safin D.
dc.contributor.author Rakhmatullin A.
dc.contributor.author Fayon F.
dc.contributor.author Zabirov N.
dc.contributor.author Bolte M.
dc.contributor.author Brusko V.
dc.contributor.author Galezowska J.
dc.contributor.author Kozlowski H.
dc.date.accessioned 2018-09-18T20:22:53Z
dc.date.available 2018-09-18T20:22:53Z
dc.date.issued 2007
dc.identifier.issn 1477-9226
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/139288
dc.description.abstract Reaction of the potassium salts of N-thiophosphorylated thioureas of common formula RC(S)NHP(S)(OiPr)2 [R = morpholin-N-yl (HLa), piperidin-N-yl (HLb), NH2 (HLc), PhCH 2NH (HLd)] with Cu(PPh3)3I in aqueous EtOH/CH2Cl2 leads to mononuclear [Cu(PPh 3)2L-S,S′] complexes. Using copper(i) iodide instead of Cu(PPh3)3I, polynuclear complexes [Cu n(L-S,S′)n] were obtained. The structures of these compounds were investigated by ES-MS, elemental analyses, 1H and 31P NMR in solution, IR and 31P solid-state MAS NMR spectroscopy. The crystal structures of [Cu3L3 a] and [Cu(PPh3)2Lb] were determined by single-crystal X-ray diffraction. © The Royal Society of Chemistry 2007.
dc.relation.ispartofseries Dalton Transactions
dc.title Complexes of N-thiophosphorylthioureas (HL) with copper(I). Crystal structures of [Cu3L3] and [Cu(PPh3) 2L] chelates
dc.type Article
dc.relation.ispartofseries-issue 41
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 4693
dc.source.id SCOPUS14779226-2007-41-SID35348880858


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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