Ene reaction of 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione with dicyclopentadiene

dc.contributor.author	Kiselev V.
dc.contributor.author	Kornilov D.
dc.contributor.author	Lekomtseva I.
dc.contributor.author	Reshetnikova O.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-18T20:19:11Z
dc.date.available	2018-09-18T20:19:11Z
dc.date.issued	2015
dc.identifier.issn	1070-4280
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/138672
dc.description.abstract	© 2015 Pleiades Publishing, Ltd. The kinetics of the ene reaction of endo-dicyclopentadiene with 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione in benzene, toluene, acetonitrile, 1,2-dichloroetane, and chloroform have been studied. The reaction volumes and enthalpies have been determined, and the activation volume in toluene has been calculated from the pressure kinetic data. The "anomalous" ratio ΔV<inf>corr</inf><sup>≠</sup>/ΔV<inf>r</inf> = 1.34 corresponds to a concerted cyclic transition state, though the addition product has acyclic structure.
dc.relation.ispartofseries	Russian Journal of Organic Chemistry
dc.title	Ene reaction of 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione with dicyclopentadiene
dc.type	Article
dc.relation.ispartofseries-issue	3
dc.relation.ispartofseries-volume	51
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	382
dc.source.id	SCOPUS10704280-2015-51-3-SID84928350094

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.