Conformational Analysis of 4-Methyl-2-trimethylsiloxy-1,3,2- dioxaphosphinane

dc.contributor.author	Vereshchagina Y.
dc.contributor.author	Ishmaeva E.
dc.contributor.author	Chachkov D.
dc.contributor.author	Alimova A.
dc.date.accessioned	2018-09-18T20:19:03Z
dc.date.available	2018-09-18T20:19:03Z
dc.date.issued	2012
dc.identifier.issn	1070-4280
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/138648
dc.description.abstract	Conformational analysis of 4-methyl-2-trimethylsiloxy-1,3,2- dioxaphosphinane was performed by the dipole moment method and quantum-chemical calculations. The 1,3,2-dioxaphosphinane heteroring was found to adopt a chair conformation with equatorial orientation of the 4-methyl group and axial orientation of the irregular trimethylsiloxy substituent. The conformational equilibrium involves non-eclipsed gauche and trans conformers (the latter prevailing) interconvertible through rotation about the exocyclic P-O bond. © Pleiades Publishing, Ltd., 2012.
dc.relation.ispartofseries	Russian Journal of Organic Chemistry
dc.title	Conformational Analysis of 4-Methyl-2-trimethylsiloxy-1,3,2- dioxaphosphinane
dc.type	Article
dc.relation.ispartofseries-issue	10
dc.relation.ispartofseries-volume	48
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1326
dc.source.id	SCOPUS10704280-2012-48-10-SID84870505215

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