dc.contributor.author |
Vereshchagina Y. |
|
dc.contributor.author |
Ishmaeva E. |
|
dc.contributor.author |
Chachkov D. |
|
dc.contributor.author |
Alimova A. |
|
dc.date.accessioned |
2018-09-18T20:19:03Z |
|
dc.date.available |
2018-09-18T20:19:03Z |
|
dc.date.issued |
2012 |
|
dc.identifier.issn |
1070-4280 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/138648 |
|
dc.description.abstract |
Conformational analysis of 4-methyl-2-trimethylsiloxy-1,3,2- dioxaphosphinane was performed by the dipole moment method and quantum-chemical calculations. The 1,3,2-dioxaphosphinane heteroring was found to adopt a chair conformation with equatorial orientation of the 4-methyl group and axial orientation of the irregular trimethylsiloxy substituent. The conformational equilibrium involves non-eclipsed gauche and trans conformers (the latter prevailing) interconvertible through rotation about the exocyclic P-O bond. © Pleiades Publishing, Ltd., 2012. |
|
dc.relation.ispartofseries |
Russian Journal of Organic Chemistry |
|
dc.title |
Conformational Analysis of 4-Methyl-2-trimethylsiloxy-1,3,2- dioxaphosphinane |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
10 |
|
dc.relation.ispartofseries-volume |
48 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1326 |
|
dc.source.id |
SCOPUS10704280-2012-48-10-SID84870505215 |
|