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dc.contributor.author | Galyautdinova A. | |
dc.contributor.author | Vafina R. | |
dc.contributor.author | Kataeva O. | |
dc.contributor.author | Lodochnikova O. | |
dc.contributor.author | Gnevashev S. | |
dc.contributor.author | Gnezdilov O. | |
dc.contributor.author | Gavrilov V. | |
dc.contributor.author | Shtyrlin Y. | |
dc.contributor.author | Chmutova G. | |
dc.contributor.author | Klimovitskii E. | |
dc.date.accessioned | 2018-09-18T20:19:01Z | |
dc.date.available | 2018-09-18T20:19:01Z | |
dc.date.issued | 2010 | |
dc.identifier.issn | 1070-4280 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/138641 | |
dc.description.abstract | By oxidation of (Z)-4,7-dihydro-1,3-dithiepines with meta-chloroperbenzoic acid the corresponding 4,7-dihydro-1λ4,3-dithiepine 1-oxides were synthesized in ∼85% yield. A complete assignment of signals in the 1H and 13C NMR spectra of the compounds obtained was established. According to XRD analysis the seven-membered heterocycles crystallized in conformations chair or boat. The calculations by DFT method in the B3LYP/6-31G(d,p) version showed the possibility of conformational equilibrium of these forms in the gas phase. © 2010 Pleiades Publishing, Ltd. | |
dc.relation.ispartofseries | Russian Journal of Organic Chemistry | |
dc.title | Stereochemistry of seven-membered heterocycles: XLVII. Synthesis, NMR, XRD, and theoretical investigation of monosulfoxides of (Z)-4,7-dihydro- 1λ4,3-dithiepine series | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 2 | |
dc.relation.ispartofseries-volume | 46 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 246 | |
dc.source.id | SCOPUS10704280-2010-46-2-SID77952369612 |