dc.contributor.author |
Galyautdinova A. |
|
dc.contributor.author |
Vafina R. |
|
dc.contributor.author |
Kataeva O. |
|
dc.contributor.author |
Lodochnikova O. |
|
dc.contributor.author |
Gnevashev S. |
|
dc.contributor.author |
Gnezdilov O. |
|
dc.contributor.author |
Gavrilov V. |
|
dc.contributor.author |
Shtyrlin Y. |
|
dc.contributor.author |
Chmutova G. |
|
dc.contributor.author |
Klimovitskii E. |
|
dc.date.accessioned |
2018-09-18T20:19:01Z |
|
dc.date.available |
2018-09-18T20:19:01Z |
|
dc.date.issued |
2010 |
|
dc.identifier.issn |
1070-4280 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/138641 |
|
dc.description.abstract |
By oxidation of (Z)-4,7-dihydro-1,3-dithiepines with meta-chloroperbenzoic acid the corresponding 4,7-dihydro-1λ4,3-dithiepine 1-oxides were synthesized in ∼85% yield. A complete assignment of signals in the 1H and 13C NMR spectra of the compounds obtained was established. According to XRD analysis the seven-membered heterocycles crystallized in conformations chair or boat. The calculations by DFT method in the B3LYP/6-31G(d,p) version showed the possibility of conformational equilibrium of these forms in the gas phase. © 2010 Pleiades Publishing, Ltd. |
|
dc.relation.ispartofseries |
Russian Journal of Organic Chemistry |
|
dc.title |
Stereochemistry of seven-membered heterocycles: XLVII. Synthesis, NMR, XRD, and theoretical investigation of monosulfoxides of (Z)-4,7-dihydro- 1λ4,3-dithiepine series |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
2 |
|
dc.relation.ispartofseries-volume |
46 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
246 |
|
dc.source.id |
SCOPUS10704280-2010-46-2-SID77952369612 |
|