dc.contributor.author |
Zagumennov V. |
|
dc.contributor.author |
Sizova N. |
|
dc.contributor.author |
Lodochnikova O. |
|
dc.contributor.author |
Krivolapov D. |
|
dc.contributor.author |
Litvinov I. |
|
dc.date.accessioned |
2018-09-18T20:18:46Z |
|
dc.date.available |
2018-09-18T20:18:46Z |
|
dc.date.issued |
2013 |
|
dc.identifier.issn |
1070-3632 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/138596 |
|
dc.description.abstract |
On of the products of electrochemical phosphorylation of camphene was 2-(C-methyl-C-trialkylphosphonio) methyleneimino-10-trialkylphosphoniomethyl) bornane diperhlorates. A mechanism of their formation was suggested consisting in the rearrangement of the intermediate camphenylphosphonium dication followed by selective addition of acetonitrile and a second trialkylphosphine molecules. The diperhlorate hydrolysis was found to lead to the synthesis of 2-acetamido-10-trialkylphosphoniobornane perchlorates. The 2-(C-methyl-C- tripropylphosphonio)methyleneimino-10-tripropylphosphoniomethyl)bornane and 2-acetamidoyl-10-tripropylphosphoniobornane structures were established by the X-ray diffraction study. © 2013 Pleiades Publishing, Ltd. |
|
dc.relation.ispartofseries |
Russian Journal of General Chemistry |
|
dc.title |
Diphosphonioiminobornane diperchlorate: Electrosynthesis, crystal structure, and hydrolysis |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
7 |
|
dc.relation.ispartofseries-volume |
83 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1324 |
|
dc.source.id |
SCOPUS10703632-2013-83-7-SID84883296719 |
|