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dc.contributor.author | Zagumennov V. | |
dc.contributor.author | Sizova N. | |
dc.contributor.author | Lodochnikova O. | |
dc.contributor.author | Krivolapov D. | |
dc.contributor.author | Litvinov I. | |
dc.date.accessioned | 2018-09-18T20:18:46Z | |
dc.date.available | 2018-09-18T20:18:46Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/138596 | |
dc.description.abstract | On of the products of electrochemical phosphorylation of camphene was 2-(C-methyl-C-trialkylphosphonio) methyleneimino-10-trialkylphosphoniomethyl) bornane diperhlorates. A mechanism of their formation was suggested consisting in the rearrangement of the intermediate camphenylphosphonium dication followed by selective addition of acetonitrile and a second trialkylphosphine molecules. The diperhlorate hydrolysis was found to lead to the synthesis of 2-acetamido-10-trialkylphosphoniobornane perchlorates. The 2-(C-methyl-C- tripropylphosphonio)methyleneimino-10-tripropylphosphoniomethyl)bornane and 2-acetamidoyl-10-tripropylphosphoniobornane structures were established by the X-ray diffraction study. © 2013 Pleiades Publishing, Ltd. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.title | Diphosphonioiminobornane diperchlorate: Electrosynthesis, crystal structure, and hydrolysis | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 7 | |
dc.relation.ispartofseries-volume | 83 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1324 | |
dc.source.id | SCOPUS10703632-2013-83-7-SID84883296719 |