Hydrogen bonding of aliphatic and aromatic amines in aqueous solution: Thermochemistry of solvation

dc.contributor.author	Zaitseva K.
dc.contributor.author	Varfolomeev M.
dc.contributor.author	Solomonov B.
dc.date.accessioned	2018-09-18T20:18:37Z
dc.date.available	2018-09-18T20:18:37Z
dc.date.issued	2012
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/138572
dc.description.abstract	Thermochemistry of hydration of the aliphatic and aromatic amines was studied. Enthalpies of solution at infinite dilution of amines in water were measured using the method of solution calorimetry. A procedure of taking into account the ionization and non-specific hydration of amines in aqueous media was carried out. A method for estimating the enthalpy of hydrogen bonding of amines in aqueous solutions was suggested on the basis of a comparative analysis of the solvation enthalpies of the solutes in water and methanol. The efficiency of this method is confirmed by evaluating the hydrophobic effect enthalpy. © Pleiades Publishing, Ltd., 2012.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Hydrogen bonding of aliphatic and aromatic amines in aqueous solution: Thermochemistry of solvation
dc.type	Article
dc.relation.ispartofseries-issue	10
dc.relation.ispartofseries-volume	82
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1669
dc.source.id	SCOPUS10703632-2012-82-10-SID84870533023

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