Enthalpy of cooperative hydrogen bonding in the complexes of triethyl- and tri-n-butylamines with alcohols: Effect of the alkyl chain length

dc.contributor.author	Varfolomeev M.
dc.contributor.author	Zaitseva K.
dc.contributor.author	Rakipov I.
dc.contributor.author	Solomonov B.
dc.date.accessioned	2018-09-18T20:18:33Z
dc.date.available	2018-09-18T20:18:33Z
dc.date.issued	2010
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/138560
dc.description.abstract	The measurements of enthalpies of triethylamine and tri-n-butylamine dissolution in aliphatic alcohols and, vice versa, of aliphatic alcohols in amines were carried out. Enthalpies of specific interactions in the studied systems were calculated. The enthalpy of specific interaction determined in the alcohol medium, are significantly less than those obtained at dissolving alcohols in amines. The mechanism of specific interaction of amines with alcohols is discussed. Enthalpies of cooperative hydrogen bonds of tertiary amines with alcohol clusters are calculated. The dependences between the enthalpies of hydrogen bond and the spatial structure of interacting molecules are revealed. © 2010 Pleiades Publishing, Ltd.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Enthalpy of cooperative hydrogen bonding in the complexes of triethyl- and tri-n-butylamines with alcohols: Effect of the alkyl chain length
dc.type	Article
dc.relation.ispartofseries-issue	3
dc.relation.ispartofseries-volume	80
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	402
dc.source.id	SCOPUS10703632-2010-80-3-SID77952513534

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.