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dc.contributor.author | Vereshchagina I. | |
dc.contributor.author | Gazizova A. | |
dc.contributor.author | Ishmaeva E. | |
dc.contributor.author | Timosheva A. | |
dc.contributor.author | Chachkov D. | |
dc.contributor.author | Timosheva N. | |
dc.date.accessioned | 2018-09-18T20:18:30Z | |
dc.date.available | 2018-09-18T20:18:30Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/138551 | |
dc.description.abstract | For the first time is determined the polarity of eight-membered silocyns with planar fragments. By the methods of dipole moments and theoretical calculations (DFT B3LYP/6-31G*) of 1,3,2-dioxasilocyns is established that in these compounds occurs the conformational equilibrium of the forms bath-chair and distorted bath with the predominance of the first, in this case the bonds C(sp 3)-S and C(sp 3)-H of the exocyclic MeSCH2 group are in the not eclipsed gauche orientation relative to each other. © 2009 Pleiades Publishing, Ltd. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.title | Polarity and structure of eight-membered organosilicon compounds with planar fragments | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 6 | |
dc.relation.ispartofseries-volume | 79 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1090 | |
dc.source.id | SCOPUS10703632-2009-79-6-SID68949157456 |