dc.contributor.author |
Vereshchagina I. |
|
dc.contributor.author |
Gazizova A. |
|
dc.contributor.author |
Ishmaeva E. |
|
dc.contributor.author |
Timosheva A. |
|
dc.contributor.author |
Chachkov D. |
|
dc.contributor.author |
Timosheva N. |
|
dc.date.accessioned |
2018-09-18T20:18:30Z |
|
dc.date.available |
2018-09-18T20:18:30Z |
|
dc.date.issued |
2009 |
|
dc.identifier.issn |
1070-3632 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/138551 |
|
dc.description.abstract |
For the first time is determined the polarity of eight-membered silocyns with planar fragments. By the methods of dipole moments and theoretical calculations (DFT B3LYP/6-31G*) of 1,3,2-dioxasilocyns is established that in these compounds occurs the conformational equilibrium of the forms bath-chair and distorted bath with the predominance of the first, in this case the bonds C(sp 3)-S and C(sp 3)-H of the exocyclic MeSCH2 group are in the not eclipsed gauche orientation relative to each other. © 2009 Pleiades Publishing, Ltd. |
|
dc.relation.ispartofseries |
Russian Journal of General Chemistry |
|
dc.title |
Polarity and structure of eight-membered organosilicon compounds with planar fragments |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
6 |
|
dc.relation.ispartofseries-volume |
79 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1090 |
|
dc.source.id |
SCOPUS10703632-2009-79-6-SID68949157456 |
|