Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid

dc.contributor.author	Galkin V.
dc.contributor.author	Salin A.
dc.contributor.author	Bakhtiyarova Y.
dc.contributor.author	Sobanov A.
dc.date.accessioned	2018-09-18T20:18:29Z
dc.date.available	2018-09-18T20:18:29Z
dc.date.issued	2009
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/138549
dc.description.abstract	Kinetics of reaction of triphenylphosphine with a series of unsaturated carboxylic acids and related esters in the medium of acetic acid as well as in mixtures of acetic acid and acetonitrile was studied by spectrophotometry. The data obtained show that the process of quarternization should be described by kinetic equation of third order, the proton transfer occurs from the solvent. A stepwise mechanism of interaction including formation of prereaction complex on the reaction pathway is proposed. © 2009 Pleiades Publishing, Ltd.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.title	Kinetics and mechanism of triphenylphosphine quarternization with unsaturated carboxylic acids in the medium of acetic acid
dc.type	Article
dc.relation.ispartofseries-issue	5
dc.relation.ispartofseries-volume	79
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	919
dc.source.id	SCOPUS10703632-2009-79-5-SID67650505519

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.