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dc.contributor.author | Mikhailov O. | |
dc.contributor.author | Kazymova M. | |
dc.contributor.author | Shumilova T. | |
dc.contributor.author | Solov'Eva S. | |
dc.date.accessioned | 2018-09-18T20:18:28Z | |
dc.date.available | 2018-09-18T20:18:28Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/138547 | |
dc.description.abstract | Complex formation in the Cu(II)-dihydrazinomethanethione (H 2NHN-CS-NHNH2)-acetone ternary system in an ethanol solution containing CuCl2, dihydrazinomethanethione, and acetone, as well as on contact of gelatin-immobilized copper(II) hecacyanoferrate(II) with alkaline (pH >10) aqueous solutions containing the above organic compounds was studied. It was found that template synthesis is realized in both cases but gives different products: in the first case, a heteroligand chelate of CuL 1(OH) with 9-hydrazino-9-mercapto-4,6,6-trimethyl-2,3,7,8- tetraazanona-3,8-dienethiohydrazide and hydroxide ion is formed, while in the second, a chelate of CuL2 with 2,8,10,10,16-pentamethyl-3,4,6,7,11, 12,14,15-octaazaheptadeca-2,5,7,12,15-pentaene-5,13-dithiol. In both cases, dihydrazinomethanethione and acetone function as ligsons. A scheme of involved processes is suggested. © 2009 Pleiades Publishing, Ltd. Reerernces:. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.title | Template synthesis in the Cu(II)-dihydrazinomethanethione-acetone ternary system | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 1 | |
dc.relation.ispartofseries-volume | 79 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 24 | |
dc.source.id | SCOPUS10703632-2009-79-1-SID62249176311 |