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Solvent effect on stretching vibration frequencies of the N-H and O-H groups of diphenylamine and phenol in complexes with various proton acceptors: Cooperative effect

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dc.contributor.author Varfolomeev M.
dc.contributor.author Abaidullina D.
dc.contributor.author Klimovitskii A.
dc.contributor.author Solomonov B.
dc.date.accessioned 2018-09-18T20:18:20Z
dc.date.available 2018-09-18T20:18:20Z
dc.date.issued 2007
dc.identifier.issn 1070-3632
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/138523
dc.description.abstract Solvent effect on the stretching vibration frequencies of the O-H and N-H groups in complexes of phenol and diphenylamine with bases in aprotic and proton-donor solvents was studied by IR spectroscopy. Linear correlations of high quality were obtained between the frequencies of hydrogen-bonded O-H and N-H groups in these complexes in aprotic solvents and a new solvent parameter, S VW. The cooperative effect of a proton-donor solvent on the strength of hydrogen bonds in complexes of phenol and diphenylamine with bases was evaluated. It was demonstrated for the first time that the cooperative effect in the examined systems can lead to both strengthening and weakening of hydrogen bonds. © 2007 Pleiades Publishing, Ltd.
dc.relation.ispartofseries Russian Journal of General Chemistry
dc.title Solvent effect on stretching vibration frequencies of the N-H and O-H groups of diphenylamine and phenol in complexes with various proton acceptors: Cooperative effect
dc.type Article
dc.relation.ispartofseries-issue 10
dc.relation.ispartofseries-volume 77
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1742
dc.source.id SCOPUS10703632-2007-77-10-SID36448996162


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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