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Preparation and steric structure of 2-Alkoxy-2,5-dioxo-4,4- bis(trifluoromethyl)-7(8)-chloro-1,3,2λ5- benzodioxaphosphepins : EEffect of fluorinated fragments on the crystal packing

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dc.contributor.author Kotorova Y.
dc.contributor.author Gubaidullin A.
dc.contributor.author Mironov V.
dc.contributor.author Burnaeva L.
dc.contributor.author Dobrynin A.
dc.contributor.author Musin R.
dc.contributor.author Litvinov I.
dc.contributor.author Konovalova I.
dc.date.accessioned 2018-09-18T20:18:18Z
dc.date.available 2018-09-18T20:18:18Z
dc.date.issued 2006
dc.identifier.issn 1070-3632
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/138518
dc.description.abstract The reaction of hexafluoroacetone with 2-alkoxy-6(7)-chloro-1,3,2- benzodioxaphosphorin-4-ones yielded 7-and 8-chloro-substituted 2-alkoxy-2,5-dioxo-4,4-bis(trifluoromethyl)-1,3,2λ5- benzodioxaphosphepines. Their steric structure was studied by single-crystal X-ray diffraction. The effect of fluorinated substituents on the crystal packing of the benzophosphepines was demonstrated. Hydrolysis of these compounds gave the corresponding 4-and 5-chloro-substituted 2-(2-hydroxyphenyl)-2-oxo-1,1- bis(trifluoromethyl)-ethanols; the structure of 2-(2-hydroxy-5-chlorophenyl)-2- oxo-1,1-bis(trifluoromethyl)ethanol was also proved by single-crystal X-ray diffraction. © Pleiades Publishing, Inc., 2006.
dc.relation.ispartofseries Russian Journal of General Chemistry
dc.title Preparation and steric structure of 2-Alkoxy-2,5-dioxo-4,4- bis(trifluoromethyl)-7(8)-chloro-1,3,2λ5- benzodioxaphosphepins : EEffect of fluorinated fragments on the crystal packing
dc.type Article
dc.relation.ispartofseries-issue 3
dc.relation.ispartofseries-volume 76
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 437
dc.source.id SCOPUS10703632-2006-76-3-SID33747869243


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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