dc.contributor.author |
Sal'nikov Y. |
|
dc.contributor.author |
Boos G. |
|
dc.contributor.author |
Ryzhkina I. |
|
dc.contributor.author |
Burilov A. |
|
dc.contributor.author |
Manzhukova D. |
|
dc.date.accessioned |
2018-09-18T20:18:14Z |
|
dc.date.available |
2018-09-18T20:18:14Z |
|
dc.date.issued |
2007 |
|
dc.identifier.issn |
1070-3284 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/138504 |
|
dc.description.abstract |
The acid-basic and complexing properties of the novel compound 2,2-bis[(2,4-dihydroxy-3-methyl-aryl)ethyl]methylamine (H4L) in an aqueous isopropyl alcohol (80 vol % (CH3)2CHOH) were characterized by pH metric titration (T = 25 ± 0.1°C) and mathematical simulation of equilibria. The compound forms associates (dimers and tetramers) in the medium under study. The monomeric deprotonated species are accumulated only in a strongly alkaline medium. In an aqueous alcohol, the H4L ligand forms with Cu(II) eight mononuclear complexes, where it can be coordinated through the amino and hydroxo groups. © 2007 Pleiades Publishing, Ltd. |
|
dc.relation.ispartofseries |
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
|
dc.title |
Acid-basic properties of 2,2-Bis[(2,4-dihydroxy-3-methyl-aryl)ethyl] methylamine and its interaction with Cu(II) |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
7 |
|
dc.relation.ispartofseries-volume |
33 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
509 |
|
dc.source.id |
SCOPUS10703284-2007-33-7-SID34547159634 |
|