Ene reaction between 4-phenyl-1,2,4-triazoline-3,5-dione and hex-1-ene. The enthalpies, entropies, and volumes of activation and reaction in solution

dc.contributor.author	Kiselev V.
dc.contributor.author	Kashaeva H.
dc.contributor.author	Potapova L.
dc.contributor.author	Kornilov D.
dc.contributor.author	Konovalov A.
dc.date.accessioned	2018-09-18T20:17:39Z
dc.date.available	2018-09-18T20:17:39Z
dc.date.issued	2014
dc.identifier.issn	1066-5285
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/138397
dc.description.abstract	The rates of an ene reaction between 4-phenyl-1,2,4-triazoline-3,5-dione and hex-1-ene were studied in a temperature range of 15-40 °C and in a pressure range of 1-2013 bar. The enthalpy of reaction in 1,2-dichloroethane (-158.2±1.0 kJ mol-1), the enthalpy (51.3±0.5 kJ mol-1), entropy (122±2 J mol-1 K-1), and volume of activation (-31.0±1.0 cm3 mol-1), and the volume of this reaction (-26.6±0.3 cm3 mol-1) were determined. The high exothermic effect of the reaction suggests its irreversibility. © 2014 Springer Science+Business Media, Inc.
dc.relation.ispartofseries	Russian Chemical Bulletin
dc.subject	4-phenyl-1,2,4-triazoline-3,5-dione
dc.subject	Ene reaction
dc.subject	Hex-1-ene
dc.subject	High pressure
dc.subject	Kinetics
dc.subject	Thermochemistry
dc.title	Ene reaction between 4-phenyl-1,2,4-triazoline-3,5-dione and hex-1-ene. The enthalpies, entropies, and volumes of activation and reaction in solution
dc.type	Article
dc.relation.ispartofseries-issue	1
dc.relation.ispartofseries-volume	63
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	280
dc.source.id	SCOPUS10665285-2014-63-1-SID84906853494

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.