dc.contributor.author |
Latypova L. |
|
dc.contributor.author |
Yanilkin V. |
|
dc.contributor.author |
Kurbangalieva A. |
|
dc.contributor.author |
Berdnikov E. |
|
dc.contributor.author |
Chmutova G. |
|
dc.date.accessioned |
2018-09-18T20:17:35Z |
|
dc.date.available |
2018-09-18T20:17:35Z |
|
dc.date.issued |
2012 |
|
dc.identifier.issn |
1066-5285 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/138385 |
|
dc.description.abstract |
5-Alkoxy-3-chloro-2(5H)-furanones were synthesized by the electrochemical reduction of 5-alkoxy derivatives of mucochloric acid in acetonitrile on the lead electrode in the presence of acetic acid as a proton donor. A combined analysis of the experimental data and quantum chemical calculation of intermediates indicates the EE D C mechanism of reduction, including the tandem transfer of two electrons with chloride ion elimination at the stage of transfer of the second electron and protonation. © 2012 Springer Science+Business Media New York. |
|
dc.relation.ispartofseries |
Russian Chemical Bulletin |
|
dc.subject |
2(5H)-furanones |
|
dc.subject |
electrochemical reduction |
|
dc.subject |
mucochloric acid |
|
dc.subject |
quantum chemical calculations |
|
dc.subject |
selectivity |
|
dc.subject |
voltammetry |
|
dc.title |
Electrochemical reduction of mucochloric acid and its 5-alkoxy derivatives |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
3 |
|
dc.relation.ispartofseries-volume |
61 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
568 |
|
dc.source.id |
SCOPUS10665285-2012-61-3-SID84875740965 |
|