The association and complexation equilibria in the system D-glucitol-nickel(II)-water

dc.contributor.author	Rubanov A.
dc.contributor.author	Devyatov F.
dc.date.accessioned	2018-09-18T20:17:34Z
dc.date.available	2018-09-18T20:17:34Z
dc.date.issued	2010
dc.identifier.issn	1066-5285
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/138381
dc.description.abstract	A joint study using polarimetry, spectrophotometry, and mathematical modeling revealed the formation of 1: 1, 2: 1, and 4: 4 outer-sphere complexes of nickel(II) ions with neutral D-glucitol (H 6Glc-ol), viz., {[Ni(H 2O) n]•(H 6Glc-ol)aq} 2+, {[Ni(H 2O) n] 2•(H 6Glc-ol)aq} 4+, and {[Ni(H 2O) n] 4•[(H 6Glc-ol)aq] 4} 8+ in a weakly acidic medium. In aqueous solutions, D-glucitol forms tetramers. For each form, the constant of formation and the specific optical rotation was calculated. © 2010 Springer Science+Business Media, Inc.
dc.relation.ispartofseries	Russian Chemical Bulletin
dc.subject	aqueous solution
dc.subject	association
dc.subject	cluster
dc.subject	D-glucitol
dc.subject	equilibrium constants
dc.subject	mathematical modeling
dc.subject	nickel(II)
dc.subject	optical activity
dc.subject	outer-sphere complexation
dc.subject	tetramer
dc.title	The association and complexation equilibria in the system D-glucitol-nickel(II)-water
dc.type	Article
dc.relation.ispartofseries-issue	8
dc.relation.ispartofseries-volume	59
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1594
dc.source.id	SCOPUS10665285-2010-59-8-SID79951750117

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.