Chiral thiophosphorylated thioureas: Synthesis, structure, and cyclization reaction

dc.contributor.author	Metlushka K.
dc.contributor.author	Tufatullin A.
dc.contributor.author	Shaimardanova L.
dc.contributor.author	Sadkova D.
dc.contributor.author	Nikitina K.
dc.contributor.author	Lodochnikova O.
dc.contributor.author	Kataeva O.
dc.contributor.author	Alfonsov V.
dc.date.accessioned	2018-09-18T20:13:55Z
dc.date.available	2018-09-18T20:13:55Z
dc.date.issued	2014
dc.identifier.issn	1042-7163
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/137783
dc.description.abstract	© 2014 Wiley Periodicals, Inc. A number of chiral racemic and enanthiopure thiophosphorylated thioureas were synthesized by the reaction of 2-aminobutan-1-ol and 1-(a-aminobenzyl)-2-naphthol with O,O-diethyl thiophosphoryl isothiocyanate. It was found that such thioureas undergo the cyclization reaction under basic conditions with hydrogen sulfide elimination and the formation of thiophosphorylated oxasines. XRay single crystal diffraction revealed that the structure of thiourea is close to the prereaction state of the cyclization reaction.
dc.relation.ispartofseries	Heteroatom Chemistry
dc.title	Chiral thiophosphorylated thioureas: Synthesis, structure, and cyclization reaction
dc.type	Article
dc.relation.ispartofseries-issue	6
dc.relation.ispartofseries-volume	25
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	636
dc.source.id	SCOPUS10427163-2014-25-6-SID84915771561

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